indicate that arsenic leaching from fly ash is highly pH-dependent. At different pH range, leaching concentration depends on the solubility of different dominant As species. In addition, the existence of other elements in fly ash also influence arsenic leaching despite of initial ash pH. The maximum flux usually occurs at the first leaching ...
The hydrometallurgical leaching methodology is commonly practiced by researchers to leach the metals from the fly ash phases using mineral acids, alkalis, and other reagents . In connection with the cost beneficiation, process economy, and environmentally friendly perspective, the use of the low-cost green reagents in the leaching process is ...
The extraction of aluminium from coal fly ash (CFA) is an important industrial process and has produced commercial interest. However, the leaching kinetics of aluminium has received little attention.
With proper leaching tests, health hazards associated with municipal solid waste incineration (MSWI) ashes, i.e., incineration bottom ashes (IBA) and incineration fly ashes (IFA), can be quantitatively defined. However, it must be coupled with specific environmental scenarios to draw the proper conclusions. Several environmental stresses based on current management of MSWI ashes were …
of trace metals from fly ash, and to quantify the rate of release as a function of the composition of the ash. Thirty-two samples of Class F fly ash from pulverized coal combustion boilers were leached with seven leaching solutions simulating natural fluids. The leachate was analyzed for
Biological leaching of fly ash from municipal waste incineration by Aspergillus niger was examined in batch cultures and compared with chemical leaching. A. niger grew in the presence of up to 10% (w/v) of fly ash in the medium. In the presence of fly ash A. niger produced gluconate, whereas in its absence citrate was produced.
The SGLP (synthetic groundwater leaching procedure) test is particularly adequate for one-stage leaching of fly ash ( Hassett, 1994, Llorens, 1996 ). In the leaching column test, purified water was passed through the fly ash (100 g) in a vertical column with an internal diameter of 5 cm and a fillable height of 15 cm.
Fly ash demonstrates very good properties for the adsorption of mercury, especially that obtained from fluidized bed boilers due to the presence of unburned carbon . The obtained mercury content in the fly ash 2 sample was relatively high, and extremely high for the fly ash 1 sample, when related to fly ashes obtained from coal combustion .
In this study, we present results of leaching kinetics for As, Mo, and Se from three acidic fly ash samples. This study shows that the leachate concentrations of As, Mo, and Se increase over time. Three kinetics equations, pseudo-second order, Elovich, and power-function, are able to adequately describe the experimental leaching kinetics data.
commercial products is not intended to constitute endorsement or recommendation for use. ... Example results from Method 1313 for leaching from a coal combustion fly ash (EaFA): Titration curve (top), chromium eluate concentration (lower, left) and chromium release
@article{osti_21017344, title = {Heavy metal leaching from coal fly ash amended container substrates during Syngonium production}, author = {Li, Q S and Chen, J J and Li, Y C}, abstractNote = {Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production.
Fly ash is an industrial waste material that is repurposed as a soil stabiliser worldwide. In Thailand, many ground improvement projects utilise mixtures of cement and fly ash to stabilise weak soils. In this study, leaching mechanisms of arsenic, chromium, lead, and zinc from cement and fly ash stabilised soils were investigated in the laboratory.
In this study, therefore, the leaching of heavy metals from fly ash cement mortars was investigated by both tank leaching test and a shaken extraction test method in accordance with Ref. . In addition, a modified shaken extraction test method with the advantage of …
From the XANES results, it was observed that V(IV), Cr(III), As(V), Se(IV), and W(IV) were their main states of existence in fly ash. In terms of leaching results, large amounts of Mo and W were ...
from fly ash depends on the nature of leaching medium, solid: liquid ratio, temperature and leaching time. Key Words: Alumina, Fly ash, Leaching, Sulphuric acid. 1. INTRODUCTION Solid wastes are those organic and inorganic waste materials produced by various activities of the society, which have lost their value to the first user.
Fly ash along with other types of ashes such as pond ash, rice husk ash and grass ash along with lime, calcium chloride, sodium carbonate, etc., is used for soil stabilization, but has a tendency to pollute soil, resulting in leaching of metals and contaminating groundwater .
Because fly ash is composed of most of the noncombustible ele ments present in coal, a major concern in the use of coal fly ash is the potential environmental hazard due to the leaching of heavy metals from the ash. Results of other leaching studies indicate a wide range of concentrations of heavy metals in coal fly ash leachate.
Most of the recent papers on coal fly ash are dedicated to protect the environment from toxic constituents or the bulk recovery of the precious metal from coal fly ash. 8,9. Zhao et. al. 7. reported sulfuric acid leaching of Ga from coal fly ash for the subsequent sequential recovery of Ga using P507 and Cyanex 272. Gutiérrez et. al. 10
Furthermore, fly ash enhances concrete performance—including increased strength, improved sulfate resistance, decreased permeability, a reduction in the water/cement ratio required, and enhancement of pumpability and workability of the concrete, according to Shepherd. Of course, the other reality that needs to be dealt with is the sheer ...
The leaching of coal fly ash production is greater than the consumption. The unused during disposal is of concern for possible fly ash is disposed into the holding ponds, lagoons, land- contamination, especially for the aquatic fills and slag heaps. Disposal of huge amounts of fly ash in environment when ash is in contact with water.
protein in fly ash/slag based pozzolana cements as alter-native approach to construction technology. 2. Material and Methods . 2.1. Bacterium and Its Growth Condition . The bacterium was isolated from the crude soil samples of a hot spring at Bakreshwar, West Bengal, India. This is a facultative anaerobic and iron reducing bacterium
And several tests including compressive strength, toxicity leaching behavior, hydration products, pore structure and micromorphology of MgO-SiO 2-H 2 O (M–S–H) binders without and with MSWI fly ash were conducted. Results showed that the compressive strength of MSWI fly ash-blended samples varied from 1.8 MPa to 29.3 MPa, and the maximum ...
One-step leaching involved adding 100 mL FL to leach the fly ash, whereas two-step leaching involved dividing 100 mL of leaching solvent into two to leach the fly ash, each step with 50 mL, and so on. The experimental method was as follows: 10 g of fly ash was weighed and placed in a 500 mL conical flask. Different amounts of leaching solvent ...
leaching releases mercury from fly ash to the atmosphere. In previous work, the gaseous . 3 release of mercury during curing of concretes was determined. In this study, ... the fly ash produced in the United States is not recycled for commercial use. Instead, the fly ash is placed in a specifically designed landfill. To prevent environmental ...
The overall results suggest minimal leaching impact from fly ash use as a replacement for up to 45% of the cement fraction in typical US concrete formulations; however, scenario-specific assessment based on this leaching evaluation should be used to determine if potential environmental impacts exist.
Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions. Keywords: reduction, oxidation, MSW, fly ash, leaching
Commercial separation and purification processes Concentration Ohio coal ash-Fly Ash-Low Temperature Ash-Liquefaction Ash Leach Acid recovery Makeup acid 3/22/2017. 7 ... Percent Removal from Ash Leach Time, minutes Lutetium 1st Contact 2nd Contact 3rd …
Elemental analyses of the fly ash indicated that it contained calcium, aluminium, iron, sodium, potassium and magnesium, and that copper, lead, chromium and mercury were the dominant heavy metals it contained. As leaching time was increased the leaching concentrations of the heavy metals increased and the leaching toxicity was augmented.
The investigation focused on particulate matrices of fly ash, two commercial adsorbents (silica and alumina), and their relative effects on the uptake and leaching of Pyrene (Pyr), an organic compo...
controlling release of elements from soil-fly ash mixture is important for assessing the environmental impacts associated with using fly ash in soil stabilization. In this study, pH-dependent leaching tests were conducted to investigate the leaching behavior of …
• 31 mortars and concrete with fly ash, 21 mortars and concretes without fly ash D.S. Kosson, A. Garrabrants, R. DeLapp, H. van der Sloot (Chemosphere, 2014, 2 papers) • 2 Concrete formulations x 4 fly ashes with controls, and mortars reflecting commercial usage in US • Methods 1313 and 1315 used to characterize fly ash, reference ...
Fly ash has great sessment of the targeted fly ash before its application. Laboratory potential for use in the treatment of wastewater and flue gas, but this and field scale leaching studies involve fly ash and its blending potential is limited by the variability in the chemical composition of fly with other organic and inorganic amendments.
4 fly ash sources, representative of range of COPC leaching −Samples of fly ash currently being used in commercial mixes −2 from bituminous coals, 2 from sub-bituminous coals 0 (control), 20 and 45% fly ash replacement loadings for Portland cement Commercial concrete mix designs and micro-concretes (45% CFA only) Sample curing of 28 days, 3 ...